Line an 8-inch square pan with aluminum foil, leaving an overhang on two sides for lifting the bars out later; spray the foil lightly with cooking spray. Set pan aside.
In a large microwave‑safe bowl, combine 1 heaping cup creamy peanut butter, 1/2 cup light corn syrup, 1/2 cup granulated sugar, and 1/4 cup packed light brown sugar.
Microwave the mixture on high for 1 minute. Remove and stir; the mixture may still be granular.
Return the bowl to the microwave and heat on high for 1 more minute. Remove and stir until as smooth as possible.
Stir in 1 tablespoon vanilla extract and 3 tablespoons unsweetened natural cocoa powder until evenly combined.
Add 3 cups Rice Krispies and stir until the cereal is evenly coated with the peanut butter mixture.
Turn the cereal mixture into the prepared pan. Use a spatula to press and pack the mixture firmly and evenly into the pan, smoothing the top. Set the pan aside.
Crush or dice about 1 cup Butterfinger candy into small pieces and set aside.
In a medium microwave‑safe bowl, combine 1 cup semi‑sweet chocolate chips and 1/4 cup creamy peanut butter. Microwave on high for 1 minute, remove and stir. If not smooth, heat in 15‑second bursts, stirring between each burst, until the mixture can be stirred smooth.
Pour the chocolate–peanut butter mixture over the packed cereal base and spread evenly with a spatula.
While the chocolate layer is still wet, evenly sprinkle the crushed Butterfinger pieces over the top, pressing lightly so they adhere.
In the same medium bowl (no need to wash), place 1/4 cup semi‑sweet chocolate chips. Microwave on high for 1 minute, remove and stir; if necessary heat in 15‑second bursts until smooth. Use a spoon to drizzle this melted chocolate evenly over the Butterfinger layer.
Cover the pan loosely with foil and refrigerate for at least 3 hours or until the layers are completely set (overnight is fine).
Lift the set bars from the pan using the foil overhang and place on a cutting surface. Let sit at room temperature about 15 minutes before slicing to make cleaner cuts. Store airtight at room temperature up to 1 week, in the refrigerator up to 2 weeks, or in the freezer up to 6 months.