Chocolate is messy. It is totally ok if your mold gets drips of melted chocolate on it. It will not affect the chocolate bombs in the end and it flakes right off once hardened.
Take care to get chocolate into the entire mold and up the sides. If you can see the mold itself too much, chocolate may be thin when you remove.
Its ok to have excess chocolate inside the mold, just scoop out any that seems that over the top so you have space for filling.The outside of the mold will be smooth.